{"text_format":"2","workbook":"xls","n_sheets":7,"sheets":["Info","DD-System Setup","DD-Process Model","DD-Cost Model","EDBM-System Setup","EDBM-Process Model","EDBM-Cost Model"],"not_rendered":{"charts":1,"images":11,"macros":0,"external_links":1,"defined_names":2,"comments":0,"pivot_tables":0},"unopened":[],"bounds":{"document_bytes":16777216,"sheet_cells":100000,"run_cost":"one","rows_first":2000,"rows_last":500,"rows_between":2000,"halvings":0,"cell_chars":16384,"cell_head_chars":4096},"cells_cut":0,"cells_raw":0,"read":"whole","date_system":"1900","formulas":"cached_only"}

{"sheet":"Info","index":0,"n_rows":24,"n_cols":2,"rows_kept":24,"cut":false,"hidden":false,"merged":[],"flags":["formulas_cached_only"]}
[]
[]
[null,"Supporting Information for"]
[null,"\"Zero discharge process for foil industry waste acid reclamation: Coupling of diffusion dialysis and electrodialysis with bipolar membranes\""]
[]
[]
[null,"Jin-Xia Zhuang1, Qing Chen1, Shun Wang1, Wei-Ming Zhang*1, Wei-Guo Song*2, Li-Jun Wan2, Kun-Song Ma3 and Chun-Nian Zhang3"]
[]
[null,"1 College of Chemistry & Materials Engineering, Wenzhou University, Wenzhou 325000, P.R. China"]
[null,"2 Beijing National Laboratory for Molecular Sciences (BNLMS); Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P.R. China"]
[null,"3 Yangzhou Hongyuan Electronic Co., Ltd., Gaoyou 225600, P.R. China"]
[]
[null,"*Corresponding author. E-mail: weiming@iccas.ac.cn, wsong@iccas.ac.cn"]
[]
[]
[]
[]
[null,"Detailed information can be found in corresponding worksheets about:"]
[null,"◆ DD system setup"]
[null,"◆ DD process modeling"]
[null,"◆ DD cost modeling"]
[null,"◆ EDBM system setup"]
[null,"◆ EDBM proecss modeling"]
[null,"◆ EDBM cost modeling"]

{"sheet":"DD-System Setup","index":1,"n_rows":35,"n_cols":10,"rows_kept":35,"cut":false,"hidden":false,"merged":[[1,1,1,7]],"flags":["formulas_cached_only"]}
[]
[null,"Details of DD system setup"]
{"$rows_empty":24}
[{"$nulls":9},"DD stack parameters"]
[{"$nulls":9},"Counter current flow operation mode"]
[{"$nulls":9},"Tortuous flow path with turbulence nets"]
[{"$nulls":9},"Flow channel width 33mm"]
[{"$nulls":9},"Total length 170cm (3 hydraulic stage)"]
[{"$nulls":9},"5 Water channels and 5 Feed acid channels"]
[{"$nulls":9},"Total membrane area 0.91 m2"]
[{"$nulls":9},"Effective membrane area 0.50 m2"]
[{"$nulls":9},"(170*3.3*9 = 0.5049 m2)"]

{"sheet":"DD-Process Model","index":2,"n_rows":20,"n_cols":19,"rows_kept":20,"cut":false,"hidden":false,"merged":[[19,12,19,18],[1,1,1,10],[1,12,1,18],[2,10,3,10],[2,2,2,4],[2,5,2,7],[2,1,3,1],[2,12,2,16],[2,8,3,8],[2,9,3,9],[11,1,12,10],[18,1,18,10]],"flags":["formulas_cached_only"]}
[]
[null,"Experimental data",{"$nulls":10},"Process model for lab DD system"]
[null,"Inlet flow\n/LPH","Dialysate",null,null,"Diffusate",null,null,"Delta flow ratio1","ηH","ηAl",null,"Input DD inlet flow rate here → ",{"$nulls":4},0.625,"LPH"]
[null,null,"Flow/LPH","[Al3+]/M","[H+]/M","Flow/LPH","[Al3+]/M","[H+]/M"]
[null,0.253,0.2998,0.446,0.232,0.2057,0.0748,5.437,0.18695652173913047,0.9414504633844425,0.1031968684044686,null,0.625,"LPH",null,null,null,0.5440852661132813,"LPH"]
[null,0.373,0.4251,0.468,0.268,0.3214,0.0666,5.103,0.138337801608579,0.9350485823796729,0.09714110202928007,null,4.7,"mol/L H+ ",null,null,null,4.59637378331143,"mol/L H+"]
[null,0.503,0.5524,0.495,0.377,0.4529,0.0506,4.756,0.09960238568588464,0.9118403865607291,0.07732874459844982,null,0.59,"mol/L Al3+ ",null,null,null,0.05175793155916064,"mol/L Al3+ "]
[null,0.626,0.7017,0.4889,0.622,0.5509,0.04803,4.55,0.11996805111821096,0.851699072704244,0.07160550344794205]
[null,0.75,0.8872,0.462,0.953,0.6137,0.0538,4.37,0.1817333333333333,0.7603025891297047,0.07454685497376787,{"$nulls":6},"ηH+",0.8513427244422499]
[null,0.875,1.14,0.41,1.165,0.6093,0.0793,4.563,0.30365714285714296,0.6767304250852517,0.09368984169995864,{"$nulls":6},"ηAl3+",0.07636807583956318]
[null,1.001,1.377,0.39,1.323,0.6256,0.088,4.609,0.3750249750249749,0.6128143446896424,0.09298158973711108]
[null,"1: Delta flow ratio = (Water-Diffusate)/Water = (Dialysate-Feed)/Feed.The bold experimental data were used to establish the model, and others to validate it."]
[]
[]
[{"$nulls":12},0.7059147338867187,"LPH",null,null,null,0.625,"LPH"]
[{"$nulls":12},0.6186026810158171,"mol/L H+ ",null,null,null,0,"mol/L H+ "]
[{"$nulls":12},0.48247933593750003,"mol/L Al3+ ",null,null,null,0,"mol/L Al3+ "]
[]
[null,"Fitting results for modeling"]
[{"$nulls":12},"Model validation by extra experimental data"]

{"sheet":"DD-Cost Model","index":3,"n_rows":31,"n_cols":13,"rows_kept":31,"cut":false,"hidden":false,"merged":[[3,6,3,12],[4,6,4,9],[4,10,4,11],[3,1,3,4],[4,2,4,3]],"flags":["formulas_cached_only"]}
[]
[{"$nulls":4},"Input DD parameters here "]
[]
[null,"DD cost model according to the process model",{"$nulls":4},"Corresponding full-scale DD process model"]
[null,"Items","DD process",null,"Notes",null,"DD system operational conditions： ",null,null,null,1.25,null,"L/(h•m2)"]
[null,"Flow intensity",1.25,"L/(h•m2)","Valid in range of 0.5-2.0"]
[null,"Waste acid flow",150,"m3/day",null,null,150,"m3/day",null,null,null,130.58046386718752,"m3/day"]
[null,"Effective membrane area",5000,"m2",null,null,4.7,"mol/L H+ ",null,null,null,4.59637378331143,"mol/L H+"]
[null,"Total membrane area",6250,"m2","80% effective membrane area",null,0.59,"mol/L Al3+ ",null,null,null,0.05175793155916064,"mol/L Al3+"]
[null,"Membrane price",60,"$/m2",null,null,6.470000000000001,"mol/L Cl- ",null,null,null,4.751647577988912,"mol/L Cl-"]
[null,"Membrane cost",375000,"$"]
[null,"DD Stack cost",562500,"$","1.5 times of membrane cost",{"$nulls":6},"ηH+",0.8513427244422499]
[null,"Peripheral equipment cost",168750,"$","30% of stack cost",{"$nulls":6},"ηAl3+",0.07636807583956318]
[null,"Power,labor and others",112500,"$","20% of stack cost"]
[null,"Total cost",843750,"$"]
[{"$nulls":6},169.41953613281245,"m3/day",null,null,null,150,"m3/day"]
[null,"HCl price",60,"$/ton","31%wt concentrated HCl",null,0.6186026810158171,"mol/L H+",null,null,null,0,"mol/L H+ "]
[null,null,0.007064516129032259,"$/mol",null,null,0.48247933593750003,"mol/L Al3+",null,null,null,0,"mol/L Al3+ "]
[null,"HCl recovered",600196.6207317861,"mol/day",null,null,2.066040688828317,"mol/L Cl-",null,null,null,0,"mo/L Cl-"]
[null,"HCl in waste",104803.37926821387,"mol/day"]
[null,"Neutralization charge",0.007064516129032259,"$/mol","Same as HCl price for estimation"]
[]
[null,"Saving acid in DD process",4240.0987077503605,"$/day"]
[null,"Waste neutralization cost",740.385163217382,"$/day",null,null,null,"Flow intensity","Pay-off period"]
[null,"Pay-off period",241.0911605374247,"day",null,null,null,0.5,478.74]
[{"$nulls":7},0.75,323.95]
[{"$nulls":7},1,257.99]
[{"$nulls":7},1.25,241.09]
[{"$nulls":7},1.5,269.62]
[{"$nulls":7},1.75,343.08]
[{"$nulls":7},2,462.98]

{"sheet":"EDBM-System Setup","index":4,"n_rows":34,"n_cols":2,"rows_kept":34,"cut":false,"hidden":false,"merged":[[1,1,1,9]],"flags":["formulas_cached_only"]}
[]
[null,"Details of EDBM system"]
{"$rows_empty":26}
[null,"EDBM stack parameters"]
[null,"2-compartment stack configuration"]
[null,"Totally co-current flow"]
[" ","9 repeating cell pairs"]
[null,"Effective membrane area: 567mm x 33mm x 9 = 0.1684 m2"]
[null,"400ml/min flow rates for all streams"]

{"sheet":"EDBM-Process Model","index":5,"n_rows":31,"n_cols":13,"rows_kept":31,"cut":false,"hidden":false,"merged":[[2,12,3,12],[30,2,30,8],[16,10,16,12],[28,10,28,12],[29,10,29,12],[30,10,30,12],[28,2,28,8],[29,2,29,8],[1,1,1,12],[15,1,15,12],[16,2,16,8],[11,1,12,12],[2,1,3,1],[2,2,2,5],[2,6,2,8],[2,9,3,9],[2,10,3,10],[2,11,3,11]],"flags":["formulas_cached_only"]}
[]
[null,"Experimental data in EDBM process"]
[null,"Charge transferred (mol e)","HCl",null,null,null,"Dialysate",null,null,"Accumulated efficiency","PAC basicity","Accumulated energy (kWh)","Process time (min)"]
[null,null,"Volume (mL)","[H+] (mol/L)","[Al3+] (mmol/L)","[Cl-] (mol/L)","Volume (mL)","Alt (mol/L)","[Cl-] (mol/L)"]
[null,0,2000,0.05104,0.02,0.05208,2000,0.49,2.08,"98%1",-0.41496598639455784,0,0]
[null,1,2080,0.49058,1.61,0.49683,1940,0.5,1.663,0.9183264,-0.10866666666666669,0.0503,22.77]
[null,2,2125,0.83846,2.23,0.84887,1860,0.522,1.302,0.83982375,0.16858237547892718,0.10492,45.537]
[null,3,2170,1.08322,2.55,1.09364,1800,0.537,1.026,0.7495024666666668,0.36312849162011185,0.16632,68.406]
[null,4,2230,1.28633,2.92,1.29987,1720,0.561,0.75,0.691608975,0.554367201426025,0.23502,95.76]
[null,5,2280,1.39882,3.19,1.40923,1660,0.579,0.575,0.61744592,0.6689694876223373,0.30839,132.373]
[null,6,2360,1.4634,3.49,1.46652,1590,0.605,0.465,0.5585906666666667,0.743801652892562,0.38377,182.25]
[null,"1: The initial current efficiency comes from the datasheet of Fumasep FBM membranes, which represents the efficiency without H+ back diffusion."]
[]
[]
[]
[null,"Process model for EDBM process (lab system)"]
[null,null,"Input charge transferred in EDBM stack here →",{"$nulls":6},1.37,"mol electrons"]
[]
[null,null,2,"L",{"$nulls":7},2.07755159,"L"]
[null,null,0.05,"mol/L H+",{"$nulls":7},0.6273795048,"mol/L H+"]
[null,null,0.05,"mo/L Cl-",{"$nulls":7},0.6273795048,"mo/L Cl-"]
[]
[]
[null,null,2,"L",{"$nulls":7},1.90556727,"L"]
[null,null,0.62,"mol/L H+",{"$nulls":7},0.510578,"mol/L Alt"]
[null,null,0.489,"mol/L Al3+",{"$nulls":7},1.5294943371,"mo/L Cl-"]
[null,null,2.087,"mo/L Cl-",{"$nulls":7},0.0014621748293109915,"Basicity"]
[]
[null,null,"Accumulated current efficiency",{"$nulls":6},0.8784038596574106]
[null,null,"Accumulated energy consumption on stack",{"$nulls":6},0.07003032000000001,"kWh"]
[null,null,"Process time",{"$nulls":6},31.635166433700004,"min"]

{"sheet":"EDBM-Cost Model","index":6,"n_rows":56,"n_cols":13,"rows_kept":56,"cut":false,"hidden":false,"merged":[[2,1,2,4],[3,2,3,3],[2,6,2,12]],"flags":["formulas_cached_only"]}
[]
[{"$nulls":4},"Input parameter here"]
[null,"Cost model of EDBM process",{"$nulls":4},"Corresponding process model for full-scale system"]
[null,"Items","EDBM process",null,"Notes"]
[null,"Target basicity of PAC",0.667,null,"Basicity of recoverd polyaluminum",null,169.4,"m3/day",null,null,null,193.1990631861826,"m3/day"]
[{"$nulls":6},0.05,"mol/L H+",null,null,null,1.4005742569809145,"mol/L H+"]
[null,"Lab system",{"$nulls":4},0.05,"mo/L Cl-",null,null,null,1.4005742569809145,"mo/L Cl-"]
[null,"Charge transferred",4.963708996441106,"mol e","For 2.0 L dialysate in lab test"]
[null,"Energy consumption",0.15198725139735328,"kWh/L"]
[null,"Time consumed",65.3152128564383,"min/L",null,null,169.4,"m3/day"]
[null,"DD dialysate flow rate",22.046931136320342,"L/day",null,null,0.62,"mol/L H+",null,null,null,140.42044576889114,"m3/day"]
[null,"Effective membrane area",0.1684,"m2","9 cell pairs, 567*33mm each",null,0.489,"mol/L Al3+",null,null,null,0.5802959545309574,"mol/L Alt"]
[{"$nulls":6},2.087,"mo/L Cl-",null,null,null,0.5844552076141774,"mo/L Cl-"]
[null,"Full system"]
[null,"DD Dialysate flow rate",169.42,"m3/day","0.62M HCl+0.489M AlCl3"]
[null,"Scale up factor from lab system",7684.516223706788]
[null,"Effective membrane area",1294.072532072223,"m2"]
[null,"Total membrane area",1617.590665090279,"m2","80% effective area ratio"]
[null,"BP membrane cost",1164665.2788650007,"$","$720/m2 for FBK membrane",null,"Example 1: AlCl3 + HCl reclaimation (Target basicity 0.0%)"]
[null,"Anion membrane cost",582332.6394325003,"$","$360/m2 for AMT membrane"]
[null,"Stack cost",2620496.8774462515,"$","1.5 times of membrane cost",null,169.4,"m3/day",null,null,null,175.98102203125293,"m3/day"]
[null,"Peripheral equipment cost",1310248.4387231257,"$","50% of stack cost",null,0.05,"mol/L H+",null,null,null,0.6282989757608116,"mol/L H+"]
[null,"Capital cost",3930745.3161693774,"$",null,null,0.05,"mo/L Cl-",null,null,null,0.6282989757608116,"mo/L Cl-"]
[null,"Maintenance cost",393074.5316169378,"$/year","10% of capital cost per year"]
[null,"Available working time",330,"day/year","8000 working hours per year"]
[null,"Energy consumption",8497394.443474066,"kWh/year",null,null,169.4,"m3/day"]
[{"$nulls":6},0.62,"mol/L H+",null,null,null,161.38644571179833,"m3/day"]
[null,"Life span",2,"year",null,null,0.489,"mol/L Al3+",null,null,null,0.5106281825184066,"mol/L Alt"]
[null,"Total eneygy cost",1699478.8886948132,"$","$0.10/kWh",null,2.087,"mo/L Cl-",null,null,null,1.5285494124104435,"mo/L Cl-"]
[null,"Total maintenance cost",786149.0632338756,"$"]
[null,"Total cost",6416373.268098067,"$",null,null,"Total cost",13.617875809250528,"$/m3"]
[{"$nulls":6},"Profits",602.707767978613,"mol/m3","HCl recoveried from 1m3 dialysate"]
[null,"Energy consumption",15.198725139735329,"$/m3",null,null,null,4.257838747977944,"$/m3","reclaimed HCl profit"]
[null,"Maintenance",7.030663111166042,"$/m3",null,null,null,486.47265322857777,"mol/m3","AlCl3 recoveried from 1m3 dialysate"]
[null,"Capital",35.15331555583021,"$/m3",null,null,null,0.010237033938540065,"$/mol","AlCl3 recover cost"]
[null,"Overall EDBM basification cost",57.382703806731584,"$/m3","For dialysate above",null,null,0.04238937448670835,"$/Kg","as AlCl3∙6H2O"]
[]
[null,"Neutralization saving"]
[null,"HCl price",0.007064516129032259,"$/mol",null,null,"Example 2: Al(OH)2Cl + HCl reclaimation (Target basicity 66.7%)"]
[null,"Neutralization charge",0.007064516129032259,"$/mol","See DD cost model for details"]
[null,"Waste neutralization saving",4.380000000000001,"$/m3","For recovered PAC basicity ≥ 0",null,169.4,"m3/day",null,null,null,193.2,"m3/day"]
[{"$nulls":6},0.05,"mol/L H+",null,null,null,1.401,"mol/L H+"]
[{"$nulls":6},0.05,"mo/L Cl-",null,null,null,1.401,"mo/L Cl-"]
[]
[]
[{"$nulls":6},169.4,"m3/day"]
[{"$nulls":6},0.62,"mol/L H+",null,null,null,140.4,"m3/day"]
[{"$nulls":6},0.489,"mol/L Al3+",null,null,null,0.58,"mol/L Alt"]
[{"$nulls":6},2.087,"mo/L Cl-",null,null,null,0.584,"mo/L Cl-"]
[]
[{"$nulls":6},"Total cost",57.382703806731584,"$/m3"]
[{"$nulls":6},"Profits",1547.8347107438012,"mol/m3","HCl recoveried from 1m3 dialysate"]
[{"$nulls":7},10.934703279125564,"$/m3","reclaimed HCl profit"]
[{"$nulls":7},480.7083825265643,"mol/m3","Al(OH)2Cl recoveried from 1m3 dialysate"]
[{"$nulls":7},0.08751251706179954,"$/mol","Al(OH)2Cl recover cost"]
[{"$nulls":7},0.660471826881506,"$/Kg","as Al(OH)2Cl∙2H2O"]